期刊
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
卷 13, 期 4, 页码 645-651出版社
SPRINGER
DOI: 10.1007/s13738-015-0776-8
关键词
Oxidation; Pyridine-N-oxide; 1,2-Diphenyl-1,1,2,2-tetrahydroperoxyethane; Catalyst-free
资金
- Research Council of Bu-Ali Sina University
The catalyst-free oxidation of various pyridine derivatives and tertiary amines to their corresponding N-oxides with 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as an efficient oxidant has been developed. The methodology proved to tolerate a number of functional groups. The reactions proceeded smoothly under solvent-free and mild conditions at room temperature. All the products were easily extracted from the reaction mixtures in excellent yields. Graphical abstract The catalyst-free oxidation of various pyridine derivatives and tertiary amines to their corresponding N-oxides with 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as an efficient oxidant has been developed. The methodology proved to tolerate a number of functional groups. The reactions proceeded smoothly under solvent-free and mild conditions at room temperature. All the products were easily extracted from the reaction mixtures in excellent yields. [GRAPHICS] .
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