期刊
FARADAY DISCUSSIONS
卷 172, 期 -, 页码 311-325出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4fd00043a
关键词
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资金
- EPSRC [EP/G007314/1, EP/L001896/1]
- National Research Foundation, Energy Innovations Programme Office, Singapore
- Engineering and Physical Sciences Research Council [EP/G007314/1, EP/L001896/1, 1010312] Funding Source: researchfish
Chemical charging of single-walled carbon nanotubes (SWCNTs) and graphenes to generate soluble salts shows great promise as a processing route for electronic applications, but raises fundamental questions. The reduction potentials of highly-charged nanocarbon polyelectrolyte ions were investigated by considering their chemical reactivity towards metal salts/complexes in forming metal nanoparticles. The redox activity, degree of functionalisation and charge utilisation were quantified via the relative metal nanoparticle content, established using thermogravimetric analysis (TGA), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and X-ray photoelectron spectroscopy (XPS). The fundamental relationship between the intrinsic nanocarbon electronic density of states and Coulombic effects during charging is highlighted as an important area for future research.
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