期刊
EXPRESS POLYMER LETTERS
卷 3, 期 12, 页码 769-777出版社
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2009.95
关键词
polymer composites; carbon nanotube; electrical properties; thermal properties
资金
- 973 National Basic Research Program [2008CB617508]
- Cultivation Fund of the Key Scientific and Technical Innovation Project [708061]
- Ministry of Education of China
- Program for New Century Excellent Talents in University [NCET-08-0844]
In this paper, pristine and oxidized multi-walled carbon nanotube (MWCNT)/poly(vinylidene fluoride) (PVDF) composites were prepared and the temperature dependence of some electrical properties of these composites were studied. It is found that the transition temperature (T-t), from positive temperature coefficient (PTC) to negative temperature coefficient (NTC) effect, of the oxidized MWCNT/PVDF composites shifted to a higher temperature. The shift of the T-t of the oxidized MWCNT/PVDF composites can be attributed to the chemical functionalization of the MWCNTs. The dielectric constants of these composites are enhanced remarkably, which can be understood by the interfacial polarization effect. The largest dielectric constant of 3600 is obtained in the composite with about 8 vol% oxidized MWCNTs at 1 kHz. The dielectric constants of these composites increase firstly and then decrease with increasing temperature. However, when the temperature reaches a higher value, the dielectric constants increase again with increasing temperature. The 'wave' phenomenon of the temperature dependence of the dielectric constants can be understood by the temperature dependence of the interfacial polarization.
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