期刊
ACS NANO
卷 9, 期 3, 页码 2556-2564出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn506394r
关键词
Li-ion battery; supercapacitors; hierarchical porous; nitrogen-doped; carbon nanosheets
类别
资金
- National Natural Science Foundation (NNSF), China [50972017]
Hierarchical porous nitrogen-doped carbon (HPNC) nanosheets (NS) have been prepared via simultaneous activation and graphitization of biomass-derived natural silk. The as-obtained HPNC-NS show favorable features for electrochemical energy storage such as high specific surface area (S-BET: 2494 m(2)/g), high volume of hierarchical pores (2.28 cm(3)/g), nanosheet structures, rich N-doping (4.7%), and defects. With respect to the multiple synergistic effects of these features, a lithium-ion battery anode and a two-electrode-based supercapacitor have been prepared. A reversible lithium storage capacity of 1865 mA h/g has been reported, which is the highest for N-doped carbon anode materials to the best of our knowledge. The HPNC-NS supercapacitor's electrode in ionic liquid,electrolytes exhibit a capacitane of 242 F/g and energy density of 102 W h/kg (48W h/L), with high cycling life stability (9% loss after 10 000 cycles). Thus, a high-performance Li-ion battery and supercapacitors were successfully assembled for the same electrode material, which was obtained through a one-step and facile large-scale synthesis route. It is promising for next-generation hybrid energy storage and renewable delivery devices.
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