4.8 Article

Multiscale Ommatidial Arrays with Broadband and Omnidirectional Antireflection and Antifogging Properties by Sacrificial Layer Mediated Nanoimprinting

期刊

ACS NANO
卷 9, 期 2, 页码 1305-1314

出版社

AMER CHEMICAL SOC
DOI: 10.1021/nn5051272

关键词

moth's eye antireflection; nanoimprint lithography; hierarchical patterning; superhydrophobicity; biomimetics

资金

  1. National University of Singapore

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Moths eye inspired multiscale ommatidial arrays offer multifunctional properties of great significance in optoelectronic devices. However, a major challenge remains in fabricating these arrays on large-area substrates using a simple and scalable technique. Here we present the fabrication of these multiscale ommatidial arrays over large areas by a distinct approach called sacrificial layer mediated nanoimprinting, which involves nanoimprinting aided by a sacrificial layer. The fabricated arrays exhibited excellent pattern uniformity over the entire patterned area. Optimum dimensions of the multiscale ommatidial arrays determined by the finite-difference time domain simulations served as the design parameters for replicating the arrays on glass. A broadband suppression of reflectance to a minimum of similar to 1.4% and omnidirectional antireflection for highly oblique angles of incidence up to 70 degrees were achieved. In addition, superhydrophobicity and superior antifogging characteristics enabled the retention of optical properties even in wet and humid conditions, suggesting reliable optical performance in practical outdoor conditions. We anticipate that these properties could potentially enhance the performance of optoelectronic devices and minimize the influence of in-service conditions. Additionally, as our technique is solely nanoimprinting-based, it may enable scalable and high-throughput fabrication of multiscale ommatidial arrays.

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