期刊
EUROPEAN POLYMER JOURNAL
卷 57, 期 -, 页码 137-142出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2014.05.018
关键词
CNT; Polyaniline; Core-shell; Composite; Electrochemistry; Supercapacitor
资金
- CSIR, India
- UGC, India [F. 41-993/2012 (SR)]
An easy chemical oxidative polymerization has led to the self-assembly of carbon nanotube (CNT)-polyaniline (PANi) nanotube core-shell structures. Electron micrographs revealed the formation of ordered coaxial composite. Phase analysis and oxidation state study of the composite revealed a definite chemical interaction between the core and shell. The core-shell structures are found to be electrochemically active. The composite was found to possess a high specific capacitance of similar to 368.4 F/g. The electrochemical behavior of CNT-PANi nanotube core-shell structures was found to be not predominantly capacitive in nature. The core-shell composite offered almost a constant specific capacitance at different current densities. The composite is expedient as a working electrode material in supercapacitors. This work paves a way for designing high performance carbon nanomaterials based core-shell structures for energy storage applications. (C) 2014 Elsevier Ltd. All rights reserved.
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