期刊
EUROPEAN POLYMER JOURNAL
卷 49, 期 10, 页码 2976-2985出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2013.06.010
关键词
VLP, P22 virus like particle; ATRP, Atom transfer radical polymerization; Ruthenium(5-methacrylamidophenanthroline)(3)(2+); TRIS-acrylamide; Aminoethyl methacrylate, AEMA
资金
- US Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-07ER46477]
- National Science Foundation Graduate Research Fellowship
We have successfully used atom transfer radical polymerization (ATRP) to form linear and crosslinked polyacrylamide and polyacrylate polymers, constrained within the virus like particle (VLP) derived from the bacteriophage P22. Polymerization of Tris(hydroxymethyl)methylacrylamide was initiated, in a spatially controlled manner, using macroinitiators derived from two different mutants of P22, S39C and K118C. Initiation from the S39C mutant results in spatially confined polymer growth on the interior of P22 while initiation from the K118C site results in a polymerized VLP in which some of the polymer is partially exposed on the outside of the capsid. Using the S39C macroinitiator we have demonstrated polymerization of aminoethyl methacrylate (AEMA) monomers, crosslinked by co-polymerization with the multifunctional monomer [Ru(5-methacrylamido-phenanthroline)(3)](2+) resulting in an active photocatalytic P22 capsid particle. (C) 2013 Elsevier Ltd. All rights reserved.
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