期刊
EUROPEAN POLYMER JOURNAL
卷 48, 期 5, 页码 963-973出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2012.02.005
关键词
Lactone; Glycopolymers; Copolymerization; Reactivity ratios; Glass transition temperature; Molecular recognition
资金
- Ministerio de Ciencia e Innovacion [MAT2010-17016]
- Comunidad de Madrid and Universidad de Zulia
- JAE-doc (CSIC)
The copolymerization of two glycomonomers bearing lactonolactone and maltonolactone pendant groups with methyl acrylate is here described. The synthesis and characterization of these glycomonomers are fully presented. The analysis of monomer reactivity ratios of both copolymerization systems is performed and compared to those previously obtained for glycomonomers bearing glucosamine and gluconolactone pendant groups. The glass transition temperature is also analyzed as a function of their structure and finally, the molecular recognition behavior is tested against two lectins, Concanavalin A and Ricinus communis Agglutinin. (C) 2012 Elsevier Ltd. All rights reserved.
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