期刊
EUROPEAN POLYMER JOURNAL
卷 47, 期 9, 页码 1804-1816出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2011.06.012
关键词
Rapeseed oil; Rapeseed cake; p-Hydroxycinnamic acids; alpha,omega-Dienes; ADMET polymerization; Thiol-ene addition
资金
- German Federal Ministry of Food, Agriculture and Consumer Protection [FKZ 22023008]
Novel (co)polymers were synthesized from substances obtained from rapeseed via ADMET and thiol-ene additions. alpha,omega-Dienes derived from oleic and erucic acid were copolymerized with a ferulic acid derivative, a representative phenolic acid (p-hydroxycinnamic acid) present, for instance, in rapeseed cake. Copolymers with different ratios of these monomers were prepared via two different routes (ADMET and thiol-ene) and studied in detail. Both monomer and polymer synthesis were optimized in order to achieve high yielding synthetic procedures that meet the requirements of green chemistry. Some thermal properties of the resulting copolymer series were then studied and correlated to the co-monomer composition. (C) 2011 Elsevier Ltd. All rights reserved.
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