期刊
EUROPEAN POLYMER JOURNAL
卷 46, 期 12, 页码 2321-2332出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2010.10.001
关键词
Thiol-ene chemistry; Real-time FTIR; Photopolymerization; Fatty acids; Isomer/isomerization; Coatings
资金
- Swedish Research Council [621-2007-5723]
The free-radical induced reaction between a tri-functional thiol (2-ethyl-(hydroxymethyl)-1,3-propanediol trimercapto propionate) and two 1,2-disubstituted alkenes (methyl oleate and methyl elaidate) has been investigated under photochemical conditions. The photoreaction was monitored via time-resolved FUR, Raman and NMR spectroscopy to provide insights about the kinetics and efficiency in end-product formation. The information collected was subjected to numerical modelling using the GEPASI software using pre-established literature values for the rate coefficients in order to verify the proposed reaction scheme. The results confirm the thiol-ene reaction mechanism showing a very fast cis/trans-isomerization (<1.0 min) when compared with the total disappearance of unsaturations, indicating that the rate-limiting step controlling the reaction is the hydrogen transfer from the thiol involved in the formation of product. High thiol-ene conversions can be obtained at reasonable rates without major influence of side-reactions when performed in bulk indicating that this reaction is suitable for network forming purposes with mono-unsaturated fatty acid methyl esters derivatives. The kinetic and mechanistic information collected provides a basis for the design of new thiol-ene systems aiming at material and coating applications. (C) 2010 Elsevier Ltd. All rights reserved.
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