期刊
EUROPEAN POLYMER JOURNAL
卷 46, 期 6, 页码 1316-1327出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2010.03.011
关键词
Levopimaric acid; Diels-Alder adduct; Polyesters; Thermal properties; Dielectric properties
A novel route for the esterification of the Diels-Alder adduct between abietic acid, in its isomer form of levopimaric acid, and acrylic acid was established. The high purity Diels-Alder adduct was prepared starting from rosin acids. When the adduct was subjected to a condensation reaction in the presence of a cyclic carbonate ester and of an efficient amine catalyst, hydroxyalkyl esters were obtained. The corresponding linear polyesters were synthesized by the advanced polycondensation of the above intermediates at high temperature, under vacuum, and in the presence of some adequate polyesterification catalysts. In the work 1,3-dioxolan-2-one as cyclic carbonate ester, triethylamine as esterification catalyst, and toluene-4-sulfonic acid monohydrate or tetrabutyl titanate as polycondensation catalysts, were preferred for exemplifications. The polyesters were soluble in dimethylacetamide, trichloromethane, tetrahydrofuran, 1,1,2,2-tetrachloroethane, or 1,4-dioxane. The thermal and electric studies showed that the polymers were substances with good thermal stability and high dielectric properties. (C) 2010 Elsevier Ltd. All rights reserved.
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