期刊
EUROPEAN POLYMER JOURNAL
卷 45, 期 6, 页码 1836-1844出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2009.01.026
关键词
Dendrimer; Hydrogen-bonded; Liquid crystal; DSC; POM
Three generations of dendritic polyester macromolecules based on 5-hydroxyisophthalic acid were synthesized by the divergent growth approach. The characterization of dendritic fragments was performed using a combination of H-1 NMR, C-13 NMR spectroscopy and elemental analysis. The dendritic hydrogen-bonded supramolecular liquid crystalline complexes were prepared from different generation of dendritic acids and stilbazole derivative containing pyridyl units. The polarizing optical microscopy (POM) and differential scanning calorimetry (DSC) were used for investigation of the liquid crystalline properties of the hydrogen-bonded dendritic supramolecular complexes. (C) 2009 Elsevier Ltd. All rights reserved.
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