期刊
EUROPEAN POLYMER JOURNAL
卷 45, 期 4, 页码 1127-1138出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2009.01.016
关键词
Low dielectric constant; Polyimide; Solubility; High Tg
资金
- National Science Council through Project NSC
A series of new polyimides (Pis) containing di-tert-butyl side groups were synthesized via the polycondensation of 4-(4-amino-2-chlorophenyl)-1-(4-aminophenoxy)-2,6-di-tert-butylbenzene (3) with various aromatic tetracarboxylic dianhydrides. The introduction of the asymmetric di-tert-butyl groups and twisted-biphenyl structures is an effective way to increase the inter chain distance and decrease the intermolecular interaction and packing ability of the resulted polymers. Thus. these novel Pis exhibited low dielectric constants (2.83-3.10), low moisture absorption (0.95-1.69%), excellent solubility, and high glass transition temperatures (307-456 degrees C). The Pis derived from the new diamine and the rigid pyromellitic dianhydride (PMDA) were soluble in N-methyl-2-pyrrolidinone, N,N-dimethylacetamide, tetrahydrofuran, m-cresol, and cyclohexanone. The polymers also show good retention of storage modulus at high temperature (325 degrees C). In addition, H-1 NMR spectrum of the diamine 3 revealed that the protons of 4-aminophenoxy moiety are not chemical shift equivalent. (C) 2009 Elsevier Ltd. All rights reserved.
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