期刊
EUROPEAN POLYMER JOURNAL
卷 45, 期 5, 页码 1433-1441出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2009.02.007
关键词
Vegetable oil macromonomers; Thiol-ene; UV polymerization; Coatings; Castor oil; Radiation cure
资金
- Cooperative State Research, Education, and Extension Service
- US Department of Agriculture [2001-38202-10424]
Allyl, acrylate, and vinyl ether derivatives of castor oil were synthesized and blended with multifunctional thiols for evaluation as thiol-ene ultraviolet (UV) curable systems. The UV cured films were characterized and evaluated via ASTM tests, gel content, and dynamic mechanical analysis (DMA) as a function of time. Fourier transform infrared spectroscopy and DMA studies established that property advancement resulted from auto-oxidation, continued thiol-ene polymerization, or a combination of both mechanisms. (C) 2009 Elsevier Ltd. All rights reserved.
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