期刊
EUROPEAN POLYMER JOURNAL
卷 44, 期 1, 页码 113-123出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2007.10.028
关键词
PP/EPDM/nano-SiO(2) ternary composites; rheology; phase structure; filler-network; solid-like behavior
In this article, the rheological properties of polypropylene (PP)/ethylene-propylene-diene terpolymer (EPDM)/silicon dioxide NOD ternary composites were systematically investigated. Two kinds of iiano-SiO(2) particles (with hydrophobic (denoted as A-SiO(2) or hydrophilic (denoted as B-SiO(2))) as well as two processing methods (one-step or two-step) were first employed to prepare PP/EPDM/SiO(2) ternary composites. Then the deep mixing and morphology evolution of polymer composite with mixing time were assessed by rheological method, on the focus of formation of filler-network, and compared with scanning electron microscopy (SEM) observations. Linear viscoelastic behavior was observed for PP/EPDM and PP/SiO(2) binary system, showing no evidence of the formation of filler-network structure. However, a solid-like rheological behavior, which was attributed to the formation of the filler-network structure as confirmed by SEM observation, could be observed in some PP/EPDM/SiO(2) ternary systems, depending on the SiO(2) surface property, processing method and EPDM content. It seemed that SiO(2) with hydrophilic surface was necessary for the formation of filler-network in PP/EPDM/SiO(2) ternary system. Besides, two-step processing method made the solid-like behavior occurred at all earlier stage compared with that of a one-step processing method, also, the higher elastomer content facilitated the formation of the filler-network structure. The results were in good agreement with those reported in our previous publications [Yang H, Zhang Q, Guo M, Wang C, Du R, Fu Q. Polymer 2006;47:2106] [Yang H, Zhang X, Qu C, Li 13, Zhang L, Zhang Q, et al. Polymer 2007;48:860]. (c) 2007 Elsevier Ltd. All rights reserved.
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