期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 36, 页码 11562-11565出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b06255
关键词
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资金
- National Natural Science Foundation of China [21172140, 21372151]
- Program for Professor of Special Appointment (Dongfang Scholarship) of the Shanghai Education Committee
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary centers in moderate to excellent yields with excellent functional group tolerance. Electron-deficient arenes are generally more effective in inhibiting alkyl isomerization. The reactions proceed successfully with pyridine or 4-(dimethylamino)pyridine, while imidazolium salts slightly enhance the coupling efficiency.
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