期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 29, 页码 9230-9233出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b05404
关键词
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资金
- Office of Science, Office of Basic Energy Sciences, Materials Science and Engineering Division, U.S. Department of Energy [DE-AC02-05CH11231]
- Camille and Henry Dreyfus Foundation [EP-14-151]
Halide perovskites have attracted much attention over the past 5 years as a promising class of materials for optoelectronic applications. However, compared to hybrid organic-inorganic perovskites, the study of their pure inorganic counterparts, like cesium lead halides (CsPbX3), lags far behind. Here, a catalyst-free, solution-phase synthesis of CsPbX3 nanowires (NWs) is reported. These NWs are single-crystalline, with uniform growth direction, and crystallize in the orthorhombic phase. Both CsPbBr3 and CsPbI3 are photoluminescence active, with composition-dependent temperature and self-trapping behavior. These NWs with a well-defined morphology could serve as an ideal platform for the investigation of fundamental properties and the development of future applications in nanoscale optoelectronic devices based on all-inorganic perovskites.
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