期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 34, 页码 10898-10901出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b05692
关键词
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资金
- UIC Department of Chemistry, the National Science Foundation [CHE-1362294]
- Alfred P. Sloan Research Fellowship
A tunable bimetallic effect on product selectivity in catalytic CO2 reduction was identified using N-heteroc-yclic carbene-ligated Cu complexes. While the monometallic Cu-only system catalyzes hydroboration of CO2 with pinacolborane to produce formate exclusively, introducing a bimetallic effect with analogous Cu-Fe, Cu-W, and Cu-Mo catalysts produces mixtures of formate and CO. Within a series of isosteric catalysts, the selectivity of CO versus formate was controlled by tuning the electronic nature of the Cu/M pairing, with high selectivity for CO being achieved using a Cu-Mo catalyst.
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