期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 3, 页码 1206-1212出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5109968
关键词
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资金
- Canon Foundation
- SET Group CSR Foundation
- [25288009]
- [25102539]
- Grants-in-Aid for Scientific Research [15H00763, 14J10502, 25288009, 26248003, 15H00883, 26620016, 25102539] Funding Source: KAKEN
We report on how the transition from the bulk structure to the cluster-specific structure occurs in n-dodecanethiolate-protected gold clusters, Aun(SC12)(m). To elucidate this transition, we isolated a series of Aun(SC12)(m) in the n range from 38 to similar to 520, containing five newly identified or newly isolated clusters, Au-104(SC12)(45), Au-similar to 226(SC12)(similar to 76), Au-similar to 253(SC12)(similar to 90), Au-similar to 356(SC12()similar to 112), and Au-similar to 520(SC12)(similar to 130), using reverse-phase high-performance liquid chromatography. Low-temperature optical absorption spectroscopy, powder X-ray diffractometry, and density functional theory (DFT) calculations revealed that the Au cores of Au-144(SC12)(60) and smaller clusters have molecular-like electronic structures and non-fcc geometric structures, whereas the structures of the Au cores of larger clusters resemble those of the bulk gold. A new structure model is proposed for Au-104(SC12)(45) based on combined approach between experiments and DFT calculations.
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