期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 15, 页码 4936-4939出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b01705
关键词
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资金
- National Natural Science Foundation of China [21372202]
- New Century Excellent Talents in University [NCET-12-1086]
- Zhejiang Natural Science Fund for Distinguished Young Scholars [R14B020005]
A highly enantioselective intramolecular arylative dearomatization of indoles via palladium-catalyzed reductive Heck reactions was developed. The new strategy led to a series of optically active indolines bearing C2-quaternary stereocenters in modest to good yields with excellent enantioselectivities (up to 99% ee).
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