期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 37, 页码 11908-11911出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b07932
关键词
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资金
- Samsung
- Japan Society for Promotion of Science (JSPS)
Donor-acceptor triptycences, TPA-QNX-(CN)2 and TPA-PRZ(CN)2, were synthesized and their emissive properties were studied. They exhibited a bluegreen fluorescence with emission lifetimes on the order of a microsecond in cyclohexane at room temperature. The long lifetime emission is quenched by O-2 and is attributed to thermally activated delayed florescence (TADF). Unimolecular TADF is made possible by the separation and weak coupling due to homoconjugation of the HOMO and LUMO on different arms of the threedimensional donor acceptor triptycene. Organic light emitting devices (OLEDs) were fabricated using TPA-QNX(CN)2 and TPA-PRZ(CN)2 as emitters which displayed electroluminescence with efficiencies as high as 9.4% EQE.
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