期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 22, 页码 7015-7018出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02716
关键词
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资金
- Core Research for Evolutional Science and Technology (CREST) project from the Japan Science and Technology Agency (JST)
- Grants-in-Aid for Scientific Research [25410087] Funding Source: KAKEN
By use of the reversible trimerization of boronic acids, the series of boroxine cages 3-mer, 6-mer, and 12-mer were constructed from rationally designed diboronic acids whose bond angles between two C-B bonds are 60 degrees, 84 degrees, and 117 degrees, respectively. Boroxine cages 6-mer and 12-mer have 1.5 and 2.5 nm sized cavities, respectively.
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