期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 7, 页码 2452-2455出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja512746q
关键词
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资金
- NIH [GM095666]
- Sloan Foundation
We report the highly enantioselective addition of photogenerated alpha-amino radicals to Michael acceptors. This method features a dual-catalyst protocol that combines transition metal photoredox catalysis with chiral Lewis acid catalysis. The combination of these two powerful modes of catalysis provides an effective, general strategy to generate and control the reactivity of photogenerated reactive intermediates.
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