期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 38, 页码 12211-12214出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b07677
关键词
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资金
- MEXT, Japan
- MEXT
- Grants-in-Aid for Scientific Research [15H02177, 14J00792] Funding Source: KAKEN
Despite significant progress in the area of C-H bond functionalization of arenes, no general method has been reported for the functionalization of C-H bonds at the sterically encumbered positions of simple arenes, such as mesitylene. Herein, we report the development of the first platinum-based catalyst for C-H borylation of arenes and heteroarenes. Notably, this method exhibited high tolerance toward steric hindrance and provided rapid access to a series of 2,6-disubstituted phenylboronic esters, valuable building blocks for further elaborations.
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