期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 7, 页码 2456-2459出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja512986m
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资金
- Fonds der Chemischen Industrie
- Studienstiftung des Deutschen Volkes
- Deutsche Forschungsgemeinschaft [DFG Ga488/9-1]
Chiral iron alkyl and iron alkoxide complexes bearing boxmi pincers as stereodirecting ligands have been employed as catalysts for enantioselective hydrosilylation reactions with unprecedented activity and selectivity (TOF = 240 h(-1) at -40 degrees C, ee up to 99% for alkyl aryl ketones), which match the performance of previously established noble-metal-based catalysts. This shows the potential of earth-abundant metals such as iron for replacing platinum-metals without any drawbacks for the reaction design.
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