期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 15, 页码 4948-4951出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02306
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资金
- Lundbeck Foundation
- EPSRC [EP/F03623X/1]
- COST Action [CM1005]
- Augustinus Fonden
- Oticon Fonden
- Engineering and Physical Sciences Research Council [EP/F03623X/1, EP/K03927X/1, EP/J00961X/1] Funding Source: researchfish
- EPSRC [EP/J00961X/1, EP/K03927X/1, EP/F03623X/1] Funding Source: UKRI
Biotin[6]uril hexaesters represent a new class of anionophores which operate solely through C-H center dot center dot center dot anion interactions. The use of soft H-bond donors favors the transport of less hydrophilic anions (e.g., Cl-, NO3-) over hard, stongly hydrated anions (e.g., HCO3- and SO42-). Especially relevant is the selectivity between chloride and bicarbonate, the major inorganic anions in biological systems.
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