期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 8, 页码 2852-2855出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b00546
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资金
- JSPS [25620082]
A 4,4'-bipyridine-based catalyst system for diboration of pyrazine derivatives was established. The catalyst cycle consists of the following two steps: (1) reductive addition of the boron-boron bond of bis(pinacolato)diboron to 4,4'-bipyridine to form N,N'-diboryl-4,4'-bipyridinylidene and (2) oxidative boryl transfer from the intermediate to pyrazine to give N,N'-diboryl-1,4-dihydropyrazine with regeneration of 4,4'-bipyridine.
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