期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 7, 页码 2472-2475出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b00004
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [26288044, 26620075, 26105708, 26870120]
- Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [26870120, 26288044, 26105708, 15K13687, 26620075] Funding Source: KAKEN
Enantioselective propargylic etherification of propargylic esters with not only aliphatic alcohols but also phenols in the presence of a catalytic amount of copper-Pybox complex gives the corresponding propargylic ethers in good to high yields with a high to excellent enantioselectivity (up to 99% ee). The result described here provides the first successful example of enantioselective propargylic etherification
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