期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 17, 页码 5682-5685出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b03113
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [24550141]
- MEXT
- Grants-in-Aid for Scientific Research [15H03819, 24550141] Funding Source: KAKEN
Intramolecular transfer of (Bu3PPd)-Bu-t(0) on a carbon carbon double bond (C=C) was investigated by using Suzuki-Miyaura coupling reaction of dibromostilbenes with aryl boronic acid or boronic acid esters in the presence of various additives containing C=C as a model. Substituent groups at the ortho position of C=C of stilbenes are critical for selective intramolecular catalyst transfer and may serve to suppress formation of the bimolecular C=C-Pd-C=C complex that leads to intermolecular transfer of (Bu3PPd)-Bu-t(0).
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