期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 47, 页码 14830-14833出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b08279
关键词
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资金
- National Science Foundation for Young Scientists of China [21202156]
- National Natural Science Foundation of China [21372210]
- State Key Program of National Natural Science Foundation of China [21432009]
Copper-catalyzed highly efficient hydrosilylation reaction of enynoates was developed. Under simple reaction conditions, various di-, tri-, and tetrasubstituted racemic allene products could be obtained in high yields. The asymmetric 1,6-addition of silyl group to the (Z)-2-alken-4-ynoates could be achieved under mild reaction conditions to afford the silyl-substituted enantioenriched chiral allene products in good yields and with high enantioselectivities.
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