期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 50, 页码 15648-15651出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b10971
关键词
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资金
- National Basic Research Program of China [973-2015CB856600]
- National Nature Science Foundation of China [21225210, 21532009, 21421091, 21472217]
The first catalytic trifluoromethoxylation of unactivated alkenes has been developed, in which Pd(CH3CN)(2)Cl-2 was used as catalyst, AgOCF3 as trifluoromethoxide source, and Selectfluor-BF4 as oxidant. A variety of 3-OCF3 substituted piperidines were selectively obtained in good yields. Direct evidence was provided to address the facile reductive elimination of Pe(IV)-OCF3 complex to form sp(3) C-OCF3 bond.
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