期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 4, 页码 1663-1672出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5123528
关键词
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资金
- ARPA-e of the U.S. Department of Energy through the Methane Opportunities for Vehicular Energy (MOVE) program [DE-AR0000249]
- Welch Foundation [A-1725]
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, and Office of Basic Energy Sciences [DE-SC0001015]
A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications
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