期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 30, 页码 9559-9562出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b06068
关键词
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资金
- European Research Council [ERC AdG 247014]
- Swedish Research Council
- Berzelius Center EXSELENT
Herein we report an example of tandem. oxidative acetoxylation/carbocyclization of arylallenes 1 using Pd(OAc)(2). The catalytic protocol is highly selective and provides access to new C-C and C-O bonds leading to a carbocyclization. The reaction proceeds via C-H activation by Pd. Mechanistic investigations show that the C-H activation is not the rate-limiting step and indicate that the reaction proceeds via acetoxylation of the allene.
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