期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 17, 页码 5678-5681出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b03243
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资金
- ICIQ Foundation
- European Research Council [ERC 278541 - ORGA-NAUT]
- Marie Curie COFUND [291787-ICIQ-IPMP]
- MINECO [COFUND2014-51588]
- MINECO through the Severo Ochoa Excellence Accreditation [SEV-2013-0319]
- ICREA Funding Source: Custom
The visible-light-driven, phase-transfer-catalyzed, enantioselective perfluoroalkylation and trifluoro-methylation of cyclic beta-ketoesters is described. The photo-organocatalytic process, which occurs at ambient temperature and under visible light illumination, is triggered by the photochemical activity of in situ-generated electron donor-acceptor complexes, arising from the association of chiral enolates and perfluoroalkyl iodides. Preliminary mechanistic studies are reported.
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