期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 40, 页码 12800-12803出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b09135
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资金
- National Basic Research Program of China (973 Program) [2012CB821600]
- Natural Science Foundation of China [21472004, 21332002]
The first Pd(0)-catalyzed carbene insertion into Si-Si and Sn-Sn bonds has been realized by using N-tosylhydrazones as the carbene precursors. Geminal bis(silane) and geminal bis(stannane) derivatives were obtained in good to excellent yields under mild conditions. Migratory insertion of Pd carbene is supposed to be the key step for the reaction.
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