期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 51, 页码 16038-16042出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b06524
关键词
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资金
- U.S. National Science Foundation [CHE-1402004]
- Robert A. Welch Foundation [F-1018]
- Australian Research Council [FT120100101]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1402004] Funding Source: National Science Foundation
- Australian Research Council [FT120100101] Funding Source: Australian Research Council
Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P1) and phenyl C-61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
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