4.8 Article

Olefin Oxygenation by Water on an Iridium Center

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 19, 页码 6168-6171

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AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b03055

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  1. DST
  2. CSIR

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Oxygenation of 1,5-cyclooctadietie (GOD) is achieved on an iridium center using water as a reagent. A :hydrogen-bonding interaction with an unbound nitrogen atom of the naphthyridine-based ligand architecture promotes nucleophilic attack of water to the metal-bound COD: Irida-oxetane and oxo-irida-allyl compounds are,isolated, products which are normally accessed froin reactions with H2O2 or O-2. DFT studies support a ligand-assisted water activation mechanism.

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