期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 18, 页码 5863-5866出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b01253
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资金
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning and Education [2014R1A1A1002224, 2014R1A1A2056364]
- NSF [1212799]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1212799] Funding Source: National Science Foundation
- National Research Foundation of Korea [2014R1A1A2056364, 2014R1A1A1002224] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Stoichiometric control of Ru, Ag, and tetrazolyl ligands resulted in the formation of different heterometallic Ru-Ag supramolecular architectures. Although the reaction of Ru and 5-(2-hydroxyphenyl)-1H-tetrazolyl (LH2) in a molar ratio of 2:1 or 6:4 resulted in the formation of dimeric or hexameric Ru complexes, Ag metal ions caused the Ru complexes to form three-dimensional cylindrical: Ru6Ag6L6 and double-cone-shaped Ru6Ag8L6 complexes by occupying vacant coordination sites.
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