期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 34, 页码 10874-10877出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b05142
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资金
- NIH [GM101153]
Isomorphous crystals of Mn-v(O) and Cr-v(O) corrolazines were characterized by single crystal X-ray diffraction. Reactivity studies with H atom donors and separated PCET reagents show a dramatic difference in H atom abstracting abilities for these two complexes. The implied large difference in driving force is opposite the trend in redox potentials, indicating that basicity is a key factor in determining the striking difference in reactivity for two metal-oxo species in identical ligand environments.
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