期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 25, 页码 8046-8049出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b05144
关键词
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资金
- NIH/NIGMS [GM-097444]
- Fulbright ST Awards
- China Scholarship Council
A solution to the classic unsolved problem of olefin hydromethylation is presented. This highly chemoselective method can tolerate labile and reactive chemical functionalities and uses a simple set of reagents. An array of olefins, including mono-, di-, and trisubstituted olefins, are all smoothly hydromethylated. This mild protocol can be used to simplify the synthesis of a specific target or to directly edit complex natural products and other advanced materials. The method is also amenable to the simple installation of radioactive and stable labeled methyl groups.
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