期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 2-3, 页码 283-294出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800944
关键词
Frustrated Lewis pair; Hydrogen activation; Hydrogenation; Lewis acids; Lewis bases; Protodeborylation
资金
- German Science Foundation (DFG) [PA 1562/6-1, PA 1562/14-1, PA 1562/16-1]
This review summarizes the principle reaction mechanisms of frustrated Lewis pairs (FLP) in hydrogenations and carbon-nitrogen and carbon-carbon bond forming reactions. The fundamental mechanism of hydrogen activation by FLPs is reviewed and the influence of the FLP's nature on hydrogenation reactions is discussed, leading to a structure-reactivity relationship in phosphine/borane or amine/borane derived FLPs. This reactivity concept is validated for a series of FLP-catalyzed reactions. Furthermore, alternative reaction mechanisms e.g. protodeborylations or sigma-bond metathesis are discussed.
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