期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2018, 期 40, 页码 5553-5557出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801195
关键词
Small ring systems; Strained molecules; Synthetic methods; Homogeneous catalysis; Palladium; Rhodium
资金
- National Natural Science Foundation of China [21572203, 21472140]
- Zhejiang Provincial Natural Science Foundation [LZ16B020001]
Palladium- and rhodium-catalyzed selective reactions of 2H-azirines and N-(acyloxy)amides leading to alpha-amino oxime esters were described. The regioselectivities of the reactions are catalyst-controlled, and two different alpha-amino oxime esters were selectively obtained in high yields. These reactions involved the construction of new N-O and C-N bonds, which are characterized by 100 % atom economy, good to excellent yields, and mild reaction conditions.
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