期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 5, 页码 928-932出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301654
关键词
Fluorine; Decarboxylation; Sulfur; Olefination; Aldehydes
资金
- National Natural Science Foundation of China (NSFC) [21032006, 21172240]
- 973 Program of China [2012CBA01200]
- Chinese Academy of Sciences
The decarboxylation of potassium 2-pyridinyl sulfonyldifluoroacetate and its subsequent reaction with aldehydes was found to be an efficient approach for the Julia-Kocienski reaction under mild conditions to give gem-difluoro olefins in moderate to excellent yields. Owing to its high stability in the pure state and its easy decarboxylation in polar solvents, potassium 2-pyridinyl sulfonyldifluoroacetate is expected to be an efficient gem-difluoro-olefination reagent.
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