期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 20, 页码 4381-4388出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402202
关键词
Synthetic methods; Asymmetric synthesis; Chiral auxiliaries; Cross-coupling; Amines
资金
- French Ministere de l'Enseignement Superieur et de la Recherche
A new and concise method for the synthesis of enantioenriched 2-heteroaryl cyclic amines was developed through an intramolecular chirality transfer. The influence of the nature of both ring size and heteroaryl moiety was investigated. The versatility of this reaction was demonstrated by the enantioselective synthesis of (-)-anabasine.
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