期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 30, 页码 6649-6652出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403112
关键词
Electrochemistry; Redox chemistry; Amino acids; Decarboxylation; Nitriles
资金
- Industrieel Onderzoeksfonds KU Leuven [IKP/10/005]
- KU Leuven through Methusalem grant CASAS
Bromide-assisted electrochemical decarboxylation efficiently produces valuable nitriles in high yields from a wide range of naturally occurring amino acids in a single step. Bromide salts are used as both redox mediators and supporting electrolytes in a simple one-compartment setup. As demonstrated for lysine, the selectivity of the decarboxylation can be tuned towards nitriles, amines or amides.
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