期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 16, 页码 3328-3333出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402192
关键词
Homogeneous catalysis; Domino reactions; Metathesis; Isomerization; Boron
资金
- University of Rennes 1
- Centre National de la Recherche Scientifique (CNRS)
- Region Bretagne
We described the efficient preparation of (E)-(2-arylvinyl)boronates from allylbenzene derivatives on the basis of an isomerization/cross-metathesis sequence catalyzed by a modified Hoveyda-Grubbs catalyst. The implementation of the experimental procedure was simple and compatible with a large variety of substrates. This methodology provides a new chemical transformation not described to date. Allyl-substituted aromatics can thus be converted into diversely functionalized compounds, such as (E)-stilbene derivatives or (E)-vinyl azides, in only two steps.
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