期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 36, 页码 8094-8100出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403068
关键词
Copper; C-C coupling; Benzylation; Coumarins; Quinolinones; Radical reactions
资金
- National Natural Science Foundation of China [21102110, 21102111]
- Fundamental Research Funds of the Central Universities [2012jdhz28, xjj2012100]
A new copper-catalyzed regioselective cross-dehydrogenative coupling of coumarins with benzylic C-sp3-H bonds has been developed. This reaction provides direct access to a wide range of 3-benzylcoumarins in moderate to good yields. The protocol was also extended successfully to other heterocyclic compounds, such as quinolinones.
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