期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 21, 页码 4477-4481出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402597
关键词
Boron; Fluorine; Diazo compounds; Trifluoroethylation; gem-Difluorovinylation
资金
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Science Foundation of China (NSFC) [21332002, 21272010, 21172005]
The transition-metal-free 2,2,2-trifluoroethylation and gem-difluorovinylation of arylboronic acids were developed. By employing different reaction conditions, these transformations provide both (2,2,2-trifluoroethyl)arenes and gem-difluorovinylarenes from arylboronic acids and 2,2,2-trifluorodiazoethane. The operation is simple and scalable with good functional group tolerance.
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