期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 18, 页码 3917-3922出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402134
关键词
Synthetic methods; C-C coupling; Biaryls; Palladium; Sulfur
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Le Fonds de Recherche du Quebec, Nature et Technologies (FQRNT)
- Boehringer Ingelheim
- Wyeth
- Merck Frosst
- Concordia University
- Centre in Green Chemistry and Catalysis
A range of aryl sulfinates can be oxidatively dimerized to generate substituted biphenyls with concomitant extrusion of sulfur dioxide with a palladium catalyst. Catalytic amounts of TEMPO and excess oxygen are utilized as oxidants to regenerate the palladium catalyst.
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