期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 26, 页码 5769-5804出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300286
关键词
Metal-free reactions; Green chemistry; Reaction mechanisms; Heterocycles; C-H functionalization; Hypervalent iodine
Direct methods of carbon-heteroatom bond formation through functionalization of non-reactive C-H bonds represent an attractive approach to the synthesis of interesting products. This review focuses on the development of metal-free coupling methods for unactivated compounds under oxidative reaction conditions. The utility of these methods in syntheses of desired products and the mechanisms of their formation are discussed with numerous examples.
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